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DOIONLINE NO - IJASEAT-IRAJ-DOIONLINE-9062

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International Journal of Advances in Science, Engineering and Technology(IJASEAT)-IJASEAT
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Volume Issue
Issue
Volume-5, Issue-3, Spl. Iss-1  ( Aug, 2017 )
Paper Title
Removal of Malachıte Green from Aqueous Solutıon by Magnetıc Nano-Adsorbent
Author Name
Servet Tural, Erdal Ertas, Bilsen Tural
Affilition
Department of Chemistry, Faculty of Education, Dicle University, 21280, Diyarbakir, Turkey.
Pages
48-52
Abstract
Theaim of thisstudy is investigate to the equilibrium and kinetics of adsorption of malachitegreendye. Iminodiaceticacid (IDA) wasattached on them agneticallyresponsiveepoxy-magneticsupport. Theadsorptioncapacity of malachitegreen (MG) on IDA attachedmagneticnanoparticles (SCMPs-IDA) wasstudied. During the studies, variousessentialfactorsinfluencingtheadsorption, likeadsorbateconcentration, contact time and dosage have bee nmonitored. Theeffect of pHvalue of solution on adsorptioncapacitywasalsoinvestigated. Theequilibriumwasachievedwithin 120 min for the MG at pH 3.5, andthemaximumsorptioncapacitycalculatedbyapplyingtheLangmuirequationtodyeadsorptionisothermwas 26.32 mg/g (C0 = 50-250 mg/L) forthe MG at pH 3.5, 30 °C. Theeffect of initialdyeconcentration on thedynamicalbehaviors of theadsorptionwasmeasured. Todeterminetheadsorptionrates, thenonlinearfirst-orderandsecond-ordermodelswereused. Thesecond-orderkinetic model fitswellwiththedynamicaladsorptionbehavior of the MG. Thenanoparticlesfortheadsorption of thedyewereregeneratedefficientlythroughthe alkaline solutionandwerethenreused 10 timesfordyeremoval. Keywords: Magnetic adsorbent, malachitegreen, Adsorptionkinetics, Adsorptionisotherms
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