DOIONLINE 
DOIONLINE Publish In |
International Journal of Advances in Science, Engineering and Technology(IJASEAT)-IJASEAT |
 Journal Home Volume Issue |
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Issue |
Special Issue-1 ( Jun, 2015 ) | |||||||||
Paper Title |
Green Approach Towards The Synthesis Of 1-Phenyl Naphthalene Lignan And Their Derivatives | |||||||||
Author Name |
Rajdiputane, Sujatadeo, Pratikpatra, Chaitaligumgaonkar. | |||||||||
Affilition |
ARAJDIPUTANE, ASUJATADEO, APRATIKPATRA, ACHAITALIGUMGAONKAR. a Department of chemistry ,Govt. Institute of Science, R.T. Road, Civil Lines, Nagpur – 440001 (MS) India | |||||||||
Pages |
43-47 | |||||||||
Abstract |
-The use of green chemistry technique reduces the chemical waste and reaction time. Recently, it has been proved in several organic synthesis and chemical transformation. In present work, synthesis of 1-phenyl naphthalene fromβ- Benzoyl propionic acid, aryl aldehyde, acetic anhydride and pyridine was carried out and it was cyclised with PPA and sulphamic acid, by using microwave irradiation. It is a three step reaction. In first step synthesis of α-arylidineγ-phenyl δ,β- butenolide by perkin reaction, in second step synthesis of α-arylidine, β-BenzoylPropionic acid by cleavage using alcoholic sodium carbonate and In third step synthesis of 1-phenyl naphthalene by cyclisation using PPA , H2SO4, Sulphamic acid has been carried out. It has been observed that microwave irradiation method produces better yield and reduces the time period compared with conventional method. The structure of 1-phenyl naphthalene was confirmed by spectral and elemental analysis. Keywords:Microwave irradiation, 1-phenyl naphthalene, PPA, cyclisation, green chemistry | |||||||||
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